Negative electrode material for secondary battery having lithium-doped silicon-silicon oxide composite

ABSTRACT

A method for manufacturing a negative electrode material for a secondary battery with a non-aqueous electrolyte, including coating a surface of a powder with 1 to 40 mass % carbon by heat CVD treatment under an organic gas and/or vapor atmosphere at a temperature between 800° C. and 1300° C., blending lithium hydride and/or lithium aluminum hydride with the carbon-coated powder; and heating the carbon-coated powder at a temperature between 200° C. and 800° C. to be doped with lithium at a doping amount of 0.1 to 20 mass %. The powder is composed of at least one of silicon oxide represented by general formula of SiO x  (x=0.5 to 1.6) and a silicon-silicon oxide composite having a structure so that silicon particles having a size of 50 nm or less are dispersed to silicon oxide in an atomic order and/or a crystallite state, and having a Si/O molar ratio of 1/0.5 to 1/1.6.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a negative electrode material for a secondary battery with a non-aqueous electrolyte, such as a lithium ion secondary battery, to a method for manufacturing the same, and to a lithium ion secondary battery by using the same, and the material is composed of a silicon-silicon oxide-lithium composite useful for the negative electrode material for a secondary battery with a non-aqueous electrolyte.

2. Description of the Related Art

Currently lithium ion secondary batteries are widely used for mobile electronic devices, such as a mobile phone, a laptop computer, and the like, because of high energy density. In recent years, with increasing awareness of environmental issues, an attempt to use this lithium ion secondary battery as a power source for an electric automobile, which is an environmentally-friendly automobile, has become active.

However, the performance of a current lithium ion secondary battery is insufficient for application to the electric automobile in terms of capacity and cycle durability. There has been accordingly advanced development of a next generation model of the lithium ion secondary battery that has high capacity and is superior in cycle durability.

As one problem of the development of the next generation model of the lithium ion secondary battery, improvement in the performance of a negative electrode material is pointed out.

Currently carbon negative electrode materials are widely used. The development by using a material other than carbon has also advanced to sharply enhance the performance, and a representative thereof is silicon oxide.

The silicon oxide has several times as much theoretical capacity as carbon has, and there is thereby possibility that silicon oxide becomes an excellent negative electrode material.

There were, however, problems such as low first efficiency, low electronic conductivity, and low cycle durability at the beginning of the development, and various improvements have accordingly made so far.

Here, the first efficiency means a ratio of discharge capacity to charge capacity in the first charge/discharge. As a result of the low first efficiency, the energy density of the lithium ion secondary battery decreases. It is considered that the low first efficiency of silicon oxide is caused by generating a lot of lithium compounds that do not contribute to the charge/discharge at the first charge.

As a method to solve this, there has been known a method of generating the above-described lithium compounds by making silicon oxide and lithium metal or a lithium compound (lithium oxide, lithium hydroxide, lithium hydride, organolithium, and the like) react an advance, before the first charge.

For example, Patent Literature 1 discloses use of a silicon oxide that can occlude and release lithium ions as a negative electrode active material, and a negative electrode material that satisfies a relation of x>0 and 2>y>0 wherein a ratio of the number of atoms among silicon, lithium, and oxygen contained in the silicon oxide is represented by 1:x:y.

As a method for manufacturing the above-described silicon oxide that is represented by a compositional formula of Li_(x)SiO_(y) and contains lithium, there is disclosed a method in which a suboxide of silicon SiO_(y) that does not contain lithium is synthesized in advance, and lithium ions are occluded by an electrochemical reaction between the obtained suboxide of silicon SiO_(y) and lithium or a substance containing lithium. In addition, there is disclosed a method in which a simple substance of each of lithium and silicon, or a compound thereof are blended at a predetermined molar ratio, and it is heated under a non-oxidizing atmosphere or an oxygen-regulated atmosphere to synthesize.

It describes that as a starting raw material, each of oxides and hydroxides, salts such as carbonates and nitrates, organolithiums, and the like are exemplified, and although it is normally possible to synthesize at a heating temperature of 400° C. or more, a temperature of 400 to 800° C. is preferable, since a disproportionation reaction to silicon and silicon dioxide may occur at a temperature of 800° C. or more.

Moreover, Patent Literatures 2 to 4 describe that a chemical method or an electrochemical method is used as a method for preliminarily inserting lithium before storing the negative electrode active material in a battery container.

It describes that as the chemical method, a method of making the negative electrode active material directly react with lithium metal, a lithium alloy (lithium-aluminum alloy and the like), or lithium compounds (n-butyllithium, lithium hydride, lithium aluminum hydride, and the like), and a lithium insertion reaction is preferably performed at a temperature of 25 to 80° C. in the chemical method. Moreover, it discloses, as the electrochemical method, a method of discharging, at open system, oxidation reduction system in which the above-described negative electrode active material is used for a positive electrode active material and a non-aqueous electrolyte containing lithium metal, a lithium alloy, or a lithium salt is used for a negative electrode active material, and a method of charging oxidation reduction system that is composed of a non-aqueous electrolyte that contains a transition metal oxide containing lithium, the negative electrode active material, and a lithium salt, as the positive electrode active material.

Moreover, Patent Literature 5 discloses powder of silicon oxide containing lithium represented by a general formula of SiLi_(x)O_(y), in which the ranges of x and y are 0<x<1.0 and 0<y<1.5, lithium is fused, and a part of the fused lithium is crystallized. It also discloses a method for manufacturing the powder of the silicon oxide containing lithium, in which a mixture of raw material powder that generates SiO gas and metallic lithium or a lithium compound is made to react by heating under an inert gas atmosphere or under reduced pressure at a temperature of 800 to 1300° C.

It discloses that, at this point in time, silicon oxide (SiO_(z)) powder (0<z<2) and silicon dioxide powder can be used as the raw material powder that generates SiO gas, and it is used after adding reduction powder (metallic silicon compounds, and powder containing carbon) as needed. It also discloses that the metallic lithium and the lithium compounds are not restricted in particular, and as the lithium compounds, for example, lithium oxide, lithium hydroxide, lithium carbonate, lithium nitrate, lithium silicate, hydrates thereof, or the like can be used, other than the metallic lithium.

On the other hand, when electronic conductivity is low, the capacity of the lithium ion secondary battery under high load decreases, and particularly cycle durability decreases.

For improvement to enhance this electronic conductivity, Patent Literature 6 discloses a negative electrode material having an electronic conductive material layer formed on a surface of silicon oxide particles. It describes that the silicon oxide among them is silicon oxide having an elementary composition of Si and O, and is preferably a suboxide of silicon represented by SiO_(x) (0<x<2), and that it can be lithium silicate in which silicon oxide is doped with Li. It also describes that a carbon material is preferably used for a conductive material and it can be manufactured by using a CVD method, a liquid phase method, or a sintering method.

Moreover, as one improving method to enhance the cycle durability, that is, to suppress an occurrence of a decrease in the capacity even when charge/discharge are repeated, Patent Literature 7 discloses a conductive silicon composite in which a diffraction peak attributable to Si (111) is observed when x-ray diffraction, the size of silicon crystal obtained by the Scherrer method based on the half-width of a diffraction line thereof is 1 to 500 nm, and a surface of its particle is coated with carbon, the composite having a structure that crystallites of silicon are dispersed to a silicon compound, particularly, the conductive silicon composite in which the silicon compound is silicon dioxide and at least a part of the surface thereof is adhered to carbon.

There is an example of a method for manufacturing this composite in which silicon oxide is subjected to disproportionation with an organic gas and/or vapor at a temperature of 900 to 1400° C., and carbon is deposited by chemical vapor deposition treatment.

Moreover, for improvement in both of the first efficiency and cycle durability, Patent Literature 8 discloses a silicon-silicon oxide composite doped with lithium, the composite having a structure that silicon particles having a size of 0.5 to 50 nm are dispersed to silicon oxide in an atomic order and/or a crystallite state, particularly, a conductive silicon-silicon oxide-lithium composite in which the surface thereof is coated with carbon at a coating amount of 5 to 50 mass % with respect to an amount of the whole composite particles after surface treatment.

It describes a method for manufacturing this composite, the method in which silicon oxide is a lithium dopant and lithium metal and/or an organolithium compound is used to dope with lithium at a temperature of 1300° C. or less, and further a method in which a silicon-silicon oxide-lithium composite that is pulverized into a predetermined particle size is subjected to heat CVD with an organic hydrocarbon gas and/or vapor at a temperature of 900 to 1400° C. and a carbon coating is formed at a coating amount of 5 to 50 mass % with respect to an amount of the whole composite particles after surface treatment.

CITATION LIST Patent Literature

-   Patent Literature 1: Japanese Patent No. 2997741 -   Patent Literature 2: Japanese Unexamined Patent publication (Kokai)     No. 8-102331 -   Patent Literature 3: Japanese Unexamined Patent publication (Kokai)     No. 8-130011 -   Patent Literature 4: Japanese Unexamined Patent publication (Kokai)     No. 8-130036 -   Patent Literature 5: Japanese Unexamined Patent publication (Kokai)     No. 2003-160328 -   Patent Literature 6: Japanese Unexamined Patent publication (Kokai)     No. 2002-42806 -   Patent Literature 7: Japanese Patent No. 3952180 -   Patent Literature 8: Japanese Unexamined Patent publication (Kokai)     No. 2007-294423

SUMMARY OF THE INVENTION

As described above, the silicon oxide negative electrode material has been improved. However, even the most advanced art described in Patent Literature 8 is still insufficient for practical use.

That is, the conductive silicon-silicon oxide-lithium composite manufactured by the method described in Patent Literature 8 has consequently achieved extensive improvement in terms of the first efficiency but the cycle durability thereof is inferior in comparison with a conductive silicon-silicon oxide composite that is not doped with lithium.

Moreover, in another aspect, the method by using lithium metal and/or an organolithium compound as the lithium dopant makes both of reaction heat and a reaction rate high, and thereby there arises problems that it is hard to control reaction temperature, and to manufacture it in an industrial scale.

The present invention was accomplished in view of the aforementioned problems, and it is an object of the present invention to provide a negative electrode material for a secondary battery with a non-aqueous electrolyte, with which a silicon oxide negative electrode material superior in first efficiency and cycle durability to conventional ones can be mass-produced (manufactured) readily and safely even in an industrial scale, a method for manufacturing the same, and a lithium ion secondary battery using the same.

In order to accomplish the above object, the present invention provides a negative electrode material for a secondary battery with a non-aqueous electrolyte including at least: a silicon-silicon oxide composite having a structure that silicon particles having a size of 0.5 to 50 nm are dispersed to silicon oxide in an atomic order and/or a crystallite state, the silicon-silicon oxide composite having a Si/O molar ratio of 1/0.5 to 1/1.6; and a carbon coating formed on a surface of the silicon-silicon oxide composite at a coating amount of 1 to 40 mass % with respect to an amount of the silicon-silicon oxide composite, wherein at least the silicon-silicon oxide composite is doped with lithium at a doping amount of 0.1 to 20 mass % with respect to an amount of the silicon-silicon oxide composite, and a ratio I(SiC)/I(Si) of a peak intensity I(SiC) attributable to SiC of 2θ=35.8±0.2° to a peak intensity I(Si) attributable to Si of 2θ=28.4±0.2° satisfies a relation of I(SiC)/I(Si)≦0.03, when x-ray diffraction using Cu—Kα ray.

In this manner, the negative electrode material for a secondary battery with a non-aqueous electrolyte, wherein, in the silicon-silicon oxide composite that is doped with lithium and has the carbon coating formed thereon, the ratio I(SiC)/I(Si) of the peak intensity I(SiC) attributable to SiC of 2θ=35.8±0.2° to the peak intensity I(Si) attributable to Si of 2θ=28.4±0.2° satisfies the relation of I(SiC)/I(Si)≦0.03, when x-ray diffraction using Cu—Kα ray, can has a sufficiently low amount of SiC at an interface between the silicon-silicon oxide composite and the carbon coating, and thereby has good electronic conductivity and discharge capacity, and particularly good cycle durability when used for a negative electrode material.

In addition, the negative electrode material is based on the silicon-silicon oxide composite which is doped with lithium at a doping amount of 0.1 to 20 mass % with respect to an amount of the silicon-silicon oxide composite, which has the structure that silicon particles having a size of 0.5 to 50 nm and having the carbon coating formed thereon at a coating amount of 1 to 40 mass % are dispersed to silicon oxide in an atomic order and/or a crystallite state, and which has a Si/O molar ratio of 1/0.5 to 1/1.6, and thereby has higher capacity and higher cycle durability in comparison with conventional ones and is superior in particularly the first efficiency.

In this case, a peak attributable to lithium aluminate can be further observed in the negative electrode material for a secondary battery with a non-aqueous electrolyte, when the x-ray diffraction using Cu—Kα ray.

The above-described negative electrode material containing aluminum can also has a sufficiently low amount of SiC at the interface between the silicon-silicon oxide composite and the carbon coating, and thereby is superior in, particularly, the cycle durability and the first efficiency. As described later, lithium aluminum hydride containing aluminum is preferably used for doping with lithium.

Furthermore, the present invention provides a lithium ion secondary battery having at least a positive electrode, a negative electrode, and a non-aqueous electrolyte having lithium ion conductivity, wherein the negative electrode material for a secondary battery with a non-aqueous electrolyte described in the present invention is used for the negative electrode.

As described above, the negative electrode material for a secondary battery with a non-aqueous electrolyte according to the present invention enables good battery characteristics (the first efficiency and the cycle durability) when used for a negative electrode of a non-aqueous electrolyte secondary battery. The lithium ion secondary battery in which the negative electrode material for a secondary battery with a non-aqueous electrolyte according to the present invention is used is therefore superior in the battery characteristics, particularly, the first efficiency and the cycle durability.

Furthermore, the present invention provides a method for manufacturing a negative electrode material for a secondary battery with a non-aqueous electrolyte including at least: coating a surface of powder with carbon at a coating amount of 1 to 40 mass % with respect to an amount of the powder by heat CVD treatment under an organic gas and/or vapor atmosphere at a temperature between 800° C. and 1300° C., the powder being composed of at least one of silicon oxide represented by a general formula of SiO_(x) (x=0.5 to 1.6) and a silicon-silicon oxide composite having a structure that silicon particles having a size of 50 nm or less are dispersed to silicon oxide in an atomic order and/or a crystallite state, the silicon-silicon oxide composite having a Si/O molar ratio of 1/0.5 to 1/1.6; blending lithium hydride and/or lithium aluminum hydride with the powder coated with carbon; and thereafter heating the powder coated with carbon at a temperature between 200° C. and 800° C. to be doped with lithium at a doping amount of 0.1 to 20 mass % with respect to an amount of the powder.

In the case of coating with carbon by the heat CVD treatment after doping with lithium, silicon and carbon at the interface between the silicon-silicon oxide composite and the carbon coating react to accelerate generation of SiC due to the doping lithium, crystallization of silicon contained in the silicon-silicon oxide composite is accelerated, and thereby the electronic conductivity and cycle durability of the negative electrode material to be obtained in this case are not good. On the other hand, doping with lithium after coating with carbon as described above enables a sufficiently low amount of the generation of SiC at the interface between the silicon-silicon oxide composite and the carbon coating. In addition to this, it can be suppressed to excessively grow silicon crystal contained in the silicon-silicon oxide composite, and the negative electrode material can be manufactured which enables good battery characteristics, such as cycle durability, when used for a negative electrode.

Moreover, when the silicon-silicon oxide composite is coated with carbon and doped with lithium, the capacity thereof can be improved in comparison with conventional methods, and the negative electrode material for a secondary battery with a non-aqueous electrolyte can be manufactured which has improved conductivity and first efficiency.

Moreover, when the temperature of the heat CVD treatment is between 800° C. and 1300° C., crystallization of carbon contained in the carbon coating and bonding of the carbon coating and the silicon-silicon oxide composite can be promoted, a fine carbon coating with high quality can be formed with high productivity, and the negative electrode material for a secondary battery with a non-aqueous electrolyte can be manufactured which has higher capacity and is superior in the cycle durability.

Furthermore, when lithium hydride and/or lithium aluminum hydride is used as the lithium dopant, the reaction is milder in comparison with the case of using lithium metal as the lithium dopant, and it can be doped with lithium with readily controlling the temperature. In addition, silicon oxide can be more reduced in comparison with the case of using a dopant containing oxygen, such as lithium hydroxide and lithium oxide, the negative electrode material having high discharge capacity can be thereby manufactured, and it can be a method for manufacturing a high capacity negative electrode material suitable to industrial mass production.

When the powder is heated at a low temperature between 200° C. and 800° C. to be doped with lithium, SiC can be prevented from being generated, the silicon crystal contained in the silicon-silicon oxide composite can be prevented from excessively growing, and thereby the discharge capacity and the cycle durability can be surely prevented from deteriorating.

As explained above, the present invention provides the negative electrode material for a secondary battery with a non-aqueous electrolyte, with which a silicon oxide negative electrode material superior in first efficiency and cycle durability to conventional ones can be mass-produced (manufactured) readily and safely even in an industrial scale, a method for manufacturing the same, and a lithium ion secondary battery using the same.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a view showing an x-ray diffraction chart of the negative electrode material for a secondary battery with a non-aqueous electrolyte in Example 1.

FIG. 2 is a view showing an x-ray diffraction chart of the negative electrode material for a secondary battery with a non-aqueous electrolyte in Example 2.

FIG. 3 is a view showing an x-ray diffraction chart of the negative electrode material for a secondary battery with a non-aqueous electrolyte in Comparative Example 2.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Hereinafter, the present invention will be explained in more detail.

In order to achieve the above object, the present inventor has repeatedly keenly conducted studies on the problems of a conventional negative electrode material for a secondary battery with a non-aqueous electrolyte and on the solution thereof.

The present inventor has thoroughly inspected the problem of the art described in Patent Literature 8, which is the most advanced art among them, and discovered the cause of inferior electronic conductivity and cycle durability.

That is, the present inventor has found that in the conductive silicon-silicon oxide-lithium composite manufactured by the method disclosed in Patent Literature 8, the carbon coating is apt to change into SiC and the silicon is apt to crystallize when the heat CVD treatment with high heat is performed after the doping with lithium, and that this is caused by the doping with lithium.

The mechanism is not quite clear. It can be, however, considered that a part of silicon oxide is reduced by lithium and becomes silicon during the doping with lithium by using lithium metal and/or organolithium compounds, this silicon is apt to change into SiC and to crystallize as compared with silicon generated by the disproportionation, and causes deterioration of the battery characteristics, particularly, the cycle durability and the discharge capacity, when used for a negative electrolyte.

The present inventor further has repeatedly keenly conducted studies based on the above result of the studies, and consequently found that performing the heat CVD treatment before the doping with lithium is necessary to suppress the change into SiC, and that an upper limit temperature of 800° C. during the doping with lithium is necessary to strongly suppress the crystallization of silicon, the upper limit temperature of 800° C. which is lower than an upper limit temperature of 900° C. at which silicon oxide without doping lithium does not crystallize.

Moreover, the present inventor has keenly conducted also studies on a lithium dopant.

That is, in the case of using a lithium dopant containing oxygen, such as lithium hydroxide and lithium oxide, like a conventional case, instead of lithium metal and/or an organolithium compound, there arises a problem that silicon oxide cannot be reduced due to oxygen contained in its composition, and that the discharge capacity thereby decreases, although the reaction is mild. In the case of using metallic lithium, there arises a problem that an ignited state is created due to intense reaction, and that it is thereby hard to control the reaction. The present inventor accordingly has repeatedly keenly conducted studies on a method for solving these problems.

As a result, the present inventor has found that when lithium hydride or lithium aluminum hydride is used as the lithium dopant and it is heated at a temperature between 200° C. and 800° C., the equivalent of the capacity in the case of using lithium metal and/or the organolithium compound can be obtained, the reaction is mild, thereby the temperature can be readily controlled, and doping with lithium can be performed in an industrial scale.

The present inventor has found, based on the above result of the studies, that in the event that after coating, with carbon, the surface of silicon oxide or the composite that is constituted by silicon particles being dispersed to silicon oxide, lithium hydride and/or lithium aluminum hydride as the lithium dopant is added thereto and they are heated at a temperature between 200° C. and 800° C., the reaction is mild, thereby the temperature can be readily controlled, and the doping with lithium can be readily performed in an industrial scale with the change into SiC and the crystallization suppressed. The present inventor has also found that use of the above-described negative electrode material as a negative electrode active material of the secondary battery with a non-aqueous electrolyte, such as the lithium ion secondary battery, enables the secondary battery with a non-aqueous electrolyte having higher capacity, higher first efficiency, and superior cycle durability in comparison with conventional methods to be obtained. The present inventor thereby brought the present invention to completion.

Hereinafter, the present invention will be explained in detail with reference to the drawings. However, the present invention is not restricted thereto.

The negative electrode material for a secondary battery with a non-aqueous electrolyte according to the present invention comprises at least: the silicon-silicon oxide composite having the structure that silicon particles having a size of 0.5 to 50 nm are dispersed to silicon oxide in an atomic order and/or a crystallite state, the silicon-silicon oxide composite having a Si/O molar ratio of 1/0.5 to 1/1.6; and the carbon coating formed on the surface of the silicon-silicon oxide composite at a coating amount of 1 to 40 mass % with respect to an amount of the silicon-silicon oxide composite.

In this negative electrode material, at least the silicon-silicon oxide composite is doped with lithium at a doping amount of 0.1 to 20 mass % with respect to an amount of the silicon-silicon oxide composite, and the ratio I(SiC)/I(Si) of the peak intensity I(SiC) attributable to SiC of 2θ=35.8±0.2° to the peak intensity I(Si) attributable to Si of 2θ=28.4±0.2° satisfies the relation of I(SiC)/I(Si)≦0.03, when the x-ray diffraction using Cu—Kα ray.

For example, it is a conductive silicon-silicon oxide-lithium composite having the carbon coating formed thereon. The negative electrode material is composed of the silicon-silicon oxide composite that has a fine structure that silicon particles having a size of 0.5 to 50 nm are dispersed to silicon oxide and/or lithium silicate in an atomic order and/or a crystallite state and has superior conductivity due to the carbon coating, superior first efficiency due to the doping with lithium, larger discharge capacity than conventional ones, and good cycle durability. It is to be noted that this dispersion structure can be observed by a transmission electron microscope.

Moreover, the ratio of the peak intensity I(SiC) attributable to SiC of 2θ=35.8±0.2° to the peak intensity I(Si) attributable to Si of 2θ=28.4±0.2° satisfies the relation of I(SiC)/I(Si)≦0.03, when x-ray diffraction using Cu—Kα ray.

This I(SiC)/I(Si) can be used as a criterion of the change of the carbon coating into SiC. In the case of I(SiC)/I(Si)>0.03, too many parts are changed into SiC in the carbon coating, and this may make a negative electrode material inferior in electronic conductivity and discharge capacity, because the generation of a large amount of SiC causes a decrease in the electronic conductivity of the interface and of the carbon coating, the capacity of the lithium ion secondary battery under high load consequently decreases, and particularly the cycle durability decreases. However, generating a very thin SiC layer at the interface between the carbon coating and the silicon-silicon oxide composite is useful for enhancing the adhesion strength of the coating.

The battery characteristics are therefore significantly deteriorated in the case of I(SiC)/I(Si)>0.03, whereas it is sufficiently permissible to be the amount of generated SiC under a condition of satisfying the relation of I(SiC)/I(Si)≦0.03, when x-ray diffraction using Cu—Kα ray. The negative electrode material for a secondary battery with a non-aqueous electrolyte according to the present invention accordingly satisfies I(SiC)/I(Si)≦0.03.

In this case, the size of the silicon particles is defined by the size D of a silicon crystallite, obtained by the Scherrer formula (1) based on the full width at half maximum of a diffraction peak of Si (111) in x-ray diffraction. D(nm)=Kλ/B cos θ  (1)

Here, K=0.9, λ=0.154 nm (in case of Cu—Kα), B=full width at half maximum (rad), θ=peak position (°).

The size of the silicon particles is desirably 0.7 to 40 nm, more desirably 1 to 30 nm.

When the particle size is 0.5 nm or more, the first efficiency can be prevented from decreasing. When the particle size is 50 nm or less, the capacity and the cycle durability can be prevented from decreasing.

Moreover, in the negative electrode material for a secondary battery with a non-aqueous electrolyte according to the preset invention, a molar ratio of Si/O contained in the silicon-silicon oxide-lithium composite is 1/0.5 to 1/1.6. When the molar ratio of oxygen to silicon is 0.5 or more, the cycle durability can be prevented from decreasing. When the molar ratio is 1.6 or less, the capacity can be prevented from decreasing.

A silicon content is desirably 10 to 60 mass %, particularly 15 to 50 mass %, more particularly 20 to 40 mass %. A silicon oxide content is desirably 40 to 90 mass %, particularly 50 to 85 mass %, more particularly 60 to 80 mass %.

Moreover, the doping amount of lithium with respect to the amount of the silicon-silicon oxide composite is 0.1 to 20 mass %, desirably 0.5 to 17 mass %, more desirably 1 to 15 mass %.

When a lithium content is 0.1 mass % or more, the first efficiency can be improved. When a lithium content is 20 mass % or less, there arises no problem of a decrease in the cycle durability and of handling safety.

It is to be noted that the carbon coating may be doped with lithium at the same time, and the content is not restricted in particular.

Moreover, an average particle size of the negative electrode material for a secondary battery with a non-aqueous electrolyte according to the present invention is desirably 1 to 50 μm, particularly 3 to 20 μm, when it is measured as a cumulative weight average value (or median diameter) D₅₀ upon measurement of particle size distribution by laser diffractometry.

The carbon coating amount is 1 to 40 mass % with respect to the amount of the silicon-silicon oxide composite coated with carbon, desirably 2 to 30 mass %, more desirably 3 to 20 mass %.

When the carbon coating amount is 1 mass % or more, the conductivity can be sufficiently improved. When the carbon coating amount is 40 mass % or less, a risk of a decrease in the discharge capacity due to too many proportions of carbon can be avoided as much as possible.

The electrical conductivity of the silicon-silicon oxide-lithium composite powder having the carbon coating formed thereon is desirably 1×10⁻⁶ S/m or more, particularly 1×10⁻⁴ S/m or more.

When the electrical conductivity is 1×10⁻⁶ S/m or more, the conductivity of the electrode becomes low, and a risk of a decrease in the cycle durability can be reduced when used as a negative electrode material for a lithium ion secondary battery.

It is to be noted that the “electrical conductivity” as used herein is a value obtained by filling a four-terminal cylindrical cell with powder to be measured and measuring a voltage drop at the time of conducting an electric current through the powder.

Moreover, the peak attributable to lithium aluminate can be further observed in the negative electrode material for a secondary battery with a non-aqueous electrolyte according to the present invention, when the x-ray diffraction using Cu—Kα ray. Moreover, the peak attributable to lithium silicate can be also observed in the negative electrode material.

Here, the lithium silicate means compounds represented by a general formula of Li_(x)SiO_(y) (1≦x≦4, 2.5≦y≦4), and the lithium aluminate means compounds represented by a general formula of Li_(x)AlO_(y) (0.2≦x≦1, 1.6≦y≦2).

That is, the doping lithium can exist mainly in a state of lithium silicate and/or lithium aluminate in the negative electrode material for a secondary battery with a non-aqueous electrolyte, and thereby lithium stably exists in the silicon-silicon oxide composite.

The negative electrode material according to the present invention can be doped with lithium by using lithium aluminum hydride containing aluminum. This negative electrode material also has a sufficiently low amount of SiC at the interface between the silicon-silicon oxide composite and the carbon coating and is superior in the cycle durability and the first efficiency.

Next, the method for manufacturing a negative electrode material for a secondary battery with a non-aqueous electrolyte according to the present invention will be explained in detail, but the method is of course not restricted thereto.

First, powder is prepared which is composed of at least one of silicon oxide represented by a general formula of SiO_(x) (0.5≦x≦1.6), and the silicon-silicon oxide composite having the structure that silicon particles having a size of 50 nm or lass are dispersed to silicon oxide in an atomic order and/or a crystallite state, the composite having a Si/O molar ratio of 1/0.5 to 1.6.

It is to be noted that this powder can be pulverized and classified in a desired particle size distribution.

The surface of the powder is coated with carbon at a coating amount of 1 to 40 mass % with respect to the amount of the powder by the heat CVD treatment under an organic gas and/or vapor atmosphere at a temperature between 800° C. and 1300° C., to give conductivity.

It is to be noted that the time of the heat CVD treatment is appropriately set according to the relation of the carbon coating amount. In the event that the prepared powder contains silicon oxide, silicon oxide changes into a silicon-silicon oxide composite due to the influence of the treatment heat.

In the event that particles aggregate during the treatment, the aggregation can be disintegrated with a ball mill and the like. When the aggregation is disintegrated, the heat CVD treatment can be performed again by the same way as above.

Specifically, the powder that is composed of at least one of silicon oxide and the silicon-silicon oxide composite is subjected to carbon coating treatment by heating to a temperature between 800° C. and 1300° C. (desirably between 900° C. and 1300° C., more desirably between 900° C. and 1200° C.) under an atmosphere containing at least an organic gas and/or vapor, by using a reactor that is heated at 800 to 1300° C. under inert gas flow.

As described above, when the temperature of the heat CVD treatment is 800° C. or more, sufficient fusion between the carbon coating and the silicon-silicon oxide composite, and sufficient alignment (crystallization) of carbon atom can be ensured. The negative electrode material for a secondary battery with a non-aqueous electrolyte that has higher capacity and is superior in the cycle durability can be therefore obtained. In addition, forming fine silicon crystal does not take long time, and it is efficient. When the temperature of the heat CVD treatment is 1300° C. or less, a risk of a deterioration in functions of the negative electrode material, which is caused by interfering with migration of lithium ion due to the development of structured crystal of a silicon dioxide part can be eliminated.

At this point in time, the silicon-silicon oxide composite powder having the carbon coating formed thereon has not been doped with lithium yet, in the present invention. The formation of SiC is thereby suppressed even when the heat CVD treatment is performed at a high temperature of 800° C. or more, particularly, 900° C. or more.

An organic material capable of producing carbon (graphite) by pyrolysis at the above-mentioned heat-treatment temperatures, particularly under a non-oxidative atmosphere, is preferably selected as an organic material used for a raw material that generates the organic gas in the present invention.

Examples of such organic materials include hydrocarbon alone or a mixture thereof, such as methane, ethane, ethylene, acetylene, propane, butane, butene, pentane, isobutane, hexane, and cyclohexane, and monocyclic to tricyclic aromatic hydrocarbons or a mixture thereof, such as benzene, toluene, xylene, styrene, ethylbenzene, diphenylmethane, naphthalene, phenol, cresol, nitrobenzene, chlorobenzene, indene, cumarone, pyridine, anthracene, phenanthrene. Additionally, gas light oils, creosote oils, anthracene oils, naphtha-cracked tar oils that are produced in the tar distillation process can be used alone or as a mixture.

As an apparatus for performing the heat CVD treatment, a reactor having a mechanism for heating an object to be treated under a non-oxidizing atmosphere may be used and it is not restricted in particular.

For example, continuous or batch-wise treatment can be performed. Specifically, a fluidized bed reactor, a rotary furnace, a vertical moving bed reactor, a tunnel furnace, a batch furnace, a rotary kiln, and the like may be selected, depending on a particular purpose.

Moreover, lithium hydride and/or lithium aluminum hydride are blended with the powder coated with carbon.

This blending is not restricted in particular as long as an apparatus that enables uniform blending under a dry atmosphere is used, and a tumbler mixer is exemplified as a small apparatus.

Specifically, a predetermined amount of the silicon-silicon oxide composite powder having the carbon coating formed thereon and of powder of lithium hydride and/or lithium aluminum hydride is weighed out in a glove box under a dry air atmosphere to put into a stainless steel sealed container. They are rotated at room temperature for a predetermined time with them set to the tumbler mixer, and blended so as to be uniform.

Lithium hydride and/or lithium aluminum hydride is used as the lithium dopant. When lithium hydride is used, the first efficiency is higher in comparison with the case of using lithium aluminum hydride having the same mass amount, and use of lithium hydride is thus better from the viewpoint of the battery characteristics. Moreover, lithium hydride may be used together with lithium aluminum hydride. Commercial lithium aluminum hydride as a reducing agent is commonly circulated, and thus can be easily obtained.

In the case of using metallic lithium and the like as the lithium dopant, the reactivity of a lithium doping agent is too high, and it is therefore necessary to perform the blending under an inert gas atmosphere, such as argon, in addition to under a dry atmosphere. On the other hand, in the case of using lithium hydride and/or lithium aluminum hydride, like the present invention, the blending can be performed under a dry atmosphere only, and is remarkably easy to handle.

Moreover, in the case of using metallic lithium and the like, a chain reaction occurs, and there is a high risk to create an ignited state. In the ignited state, there is a problem that silicon crystal is excessively grown, and the capacity and the cycle durability thereby decrease, in some cases. In case of lithium hydride and/or lithium aluminum hydride, the reaction proceeds slowly, and an increase in temperature due to reaction heat is several dozen degrees. The ignited state is not therefore created in this case, and the negative electrode material that has high capacity and is superior in the cycle durability can be readily manufactured in an industrial scale.

Moreover, in the case of using a dopant containing oxygen, such as lithium hydroxide and lithium oxide, there is a risk of the decrease in the discharge capacity, which is caused by an insufficient reduction amount of silicon oxide of the manufactured negative electrode material. On the other hand, in the case of lithium hydride and/or lithium aluminum hydride, like the present invention, such a risk can be surely avoided, and the negative electrode material having high capacity can be surely manufactured.

It is to be noted that when unreacted lithium hydride or lithium aluminum hydride is left behind, it is undesirable in both battery characteristic and safety aspects.

The lithiation reaction is solid-solid reaction between the silicon-silicon oxide composite having the carbon coating formed thereon and the lithium dopant. However, since the rate of diffusion of lithium into a solid is generally low, it is difficult for lithium to penetrate completely uniformly into the inside of the silicon-silicon oxide composite having the carbon coating formed thereon.

For safety sake, an additive amount of lithium is desirably equal to or less than an amount to supplement overall irreversible capacity (the difference between the charge capacity and the discharge capacity at the first charge/discharge), that is, Li/O≦1. To achieve this, lithium hydride or lithium aluminum hydride can be supplied in a powder or mass form, but it is desirably used in a powder form as well as the silicon-silicon oxide composite.

Thereafter, the powder coated with carbon is heated at a temperature between 200° C. and 800° C. to be doped with lithium at a doping amount of 0.1 to 20 mass % with respect to the amount of the powder.

When the doping with lithium is performed at a temperature of 200° C. or more, an insufficient reaction can be prevented. When the doping with lithium is performed at a temperature of 800° C. or less, the silicon crystal contained in the silicon-silicon oxide composite can be prevented from excessively growing, and thereby the capacity under high load and particularly the cycle durability can be surely prevented from decreasing. That is, the negative electrode material for a secondary battery with a non-aqueous electrolyte that has high capacity and is superior in the cycle durability can be manufactured.

A reactor having a heating mechanism is preferably used for the above-described lithiation reaction under an inert gas atmosphere, and the detail thereof is not restricted in particular except for a heating temperature between 200° C. and 800° C.

For example, continuous or batch-wise treatment can be performed. Specifically, a rotary furnace, a vertical moving bed reactor, a tunnel furnace, a batch furnace, a rotary kiln, and the like may be selected, depending on a particular purpose. An electric tube furnace is exemplified as a small apparatus.

More specifically, the above-described blend is put into a quartz tube through which an argon gas flows, and heated to a temperature between 200° C. and 800° C. with the electric tube furnace to react for a predetermined time.

In the event that the heat CVD treatment is performed after the powder composed of silicon oxide or the silicon-silicon oxide composite is doped with lithium, carbon reacts with silicon due to the influence of the doping lithium. The conductivity therefore decreases due to the generation of SiC, the cycle durability deteriorates due to excessive growth of the silicon crystal, and the battery characteristics thus deteriorate. However, in the case of doping with lithium at a low temperature after coating with carbon like the present invention, the generation amount of SiC at the interface between the silicon-silicon oxide composite and the carbon coating and the growth of the silicon crystal can be sufficiently suppressed, and the negative electrode material superior in the battery characteristics, such as the cycle durability, when used for a negative electrode can be obtained.

When the negative electrode material is used for a secondary battery with a non-aqueous electrolyte, the negative electrode material for a secondary battery with a non-aqueous electrolyte can be therefore obtained which has large discharge capacity and good cycle durability. In addition to this, low first efficiency, which is a fault of silicon oxide and the silicon-silicon oxide composite, is improved, in the negative electrode material.

The negative electrode material for a secondary battery with a non-aqueous electrolyte obtained according to the present invention as above can significantly contribute to the manufacture of an excellent non-aqueous electrolyte secondary battery that has high capacity and good first efficiency and is superior in the cycle durability, particularly a high performance lithium ion secondary battery, when used for the negative electrode active material of the non-aqueous electrolyte secondary battery.

In this case, the obtained lithium ion secondary battery is characterized by the use of the above-described negative electrode active material, while the materials of the positive electrode, the negative electrode, electrolyte, and separator, and the shape of the battery are not restricted.

For example, the positive electrode active material to be used may be transition metal oxides, such as LiCoO₂, LiNiO₂, LiMn₂O₄, V₂O₅, MnO₂, TiS₂, and MoS₂, and chalcogen compounds.

For example, the electrolyte to be used may be lithium salts, such as lithium perchlorate, in a non-aqueous solution form. A non-aqueous solvent to be used may be propylene carbonate, ethylene carbonate, dimethoxyethane, γ-butyrolactone and 2-methyltetrahydrofuran, alone or in admixture. Other various non-aqueous electrolytes and solid electrolytes can be also used.

It is to be noted that when the negative electrode is fabricated by using the above-described negative electrode material for a secondary battery with a non-aqueous electrolyte, a conductive agent, such as graphite, can be added to the negative electrode active material.

In this case, the type of conductive agent is not restricted in particular, as long as it is an electronically conductive material that does not cause decomposition and alteration in the manufactured battery. Specifically, the usable conductive agent includes metals in powder or fiber form, such as Al, Ti, Fe, Ni, Cu, Zn, Ag, Sn and Si, natural graphite, synthetic graphite, various coke powders, meso-phase carbon, vapor phase grown carbon fibers, pitch base carbon fibers, PAN base carbon fibers, and graphite obtained by firing various resins.

With regard to an additive amount of the above-described conductive agent, the amount of the conductive agent contained in a blend of the negative electrode material for a secondary battery with a non-aqueous electrolyte according to the present invention and the conductive agent is desirably 1 to 60 mass % (more desirably 5 to 60 mass %, particularly 10 to 50 mass %, more particularly 20 to 50 mass %).

When the additive amount of the conductive agent is 1 mass % or more, a risk of not being able to withstand expansion and contraction associated with charge/discharge can be avoided. In addition, when it is 60 mass % or less, a risk of a decrease in charge/discharge capacity can be reduced as much as possible.

When a carbon-based conductive agent is used for the negative electrode, the total amount of carbon in the negative electrode active material is desirably 5 to 90 mass % (more desirably 25 to 90 mass %, particularly 30 to 50 mass %).

When the total amount is 5 mass % or more, it can fully withstand the expansion and contraction associated with charge/discharge. In addition, when the total amount is 90 mass % or less, the charge/discharge capacity does not decrease.

EXAMPLES

Hereinafter, the present invention will be explained in more detail by showing Examples and Comparative Examples. However, the present invention is not restricted to Examples below.

It is to be noted that in Examples below, “%” indicates “mass %”, and an average particle size is measured as a cumulative weight average value (or median diameter) D₅₀ upon measurement of particle size distribution by laser diffractometry. The size of silicon crystal is a size of a crystallite of Si (111) face, obtained by the Scherrer method from data of the x-ray diffraction using Cu—Kα ray.

Example 1

Metallic silicon and silicon dioxide were blended at a molar ratio of 1:1, and reacted at 1400° C. under a reduced pressure of 100 Pa to generate a silicon oxide gas. The gas was cooled at 900° C. under a reduced pressure of 50 Pa to precipitate, and a product in mass form was consequently obtained. The product was pulverized with a dry-type ball mill to obtain powder having an average particle size of 5 μm.

Chemical analysis revealed that the composition of this powder was SiO_(0.95), the structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, and the powder was thus silicon-silicon oxide composite. The size of silicon crystal of this silicon-silicon oxide composite was 4 nm.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment by using a raw material of a methane gas at 1100° C. under a reduced pressure of 1000 Pa for 5 hours to coat the surface of the powder with carbon. As a result, the carbon coating amount was 5% of the whole powder including the coating.

Next, 2.7 g powder of lithium hydride (reagent made by Wako Pure Chemical Industries, Ltd) was put into a porcelain mortar having an internal volume of 500 ml and pulverized in a glove box under a dry air atmosphere. Thereafter, 28.4 g silicon-silicon oxide composite powder having the carbon coating formed thereon was added thereto (lithium hydride:silicon-silicon oxide composite (except carbon)=1:10 (a mass ratio)), and they were stirred and blended so as to be sufficiently uniform.

The blend of 29 g was transferred to a 70 ml alumina boat and the boat was carefully placed at the center of a furnace tube of an electric tube furnace provided with an alumina furnace tube having an inner diameter of 50 mm. It was heated up to 600° C. at 5° C. every minute while passing an argon gas at 2 liters every minute, and was cooled after holding of 1 hour.

The doping amount of lithium of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 8%. The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 10 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio of the peak intensity I(SiC) attributable to SiC of 2θ=35.8±0.2° to the peak intensity I(Si) attributable to Si of 2θ=28.4±0.2° satisfied a relation of I(SiC)/I(Si)=0, when x-ray diffraction using Cu—Kα ray, and thus the generation of SiC was suppressed. The x-ray diffraction chart thereof is shown in FIG. 1.

Example 2

Except that lithium aluminum hydride was used as the lithium dopant in Example 1, the negative electrode material for a secondary battery with a non-aqueous electrolyte was manufactured in the same conditions as Example 1, and the same evaluation was carried out.

As a result, the doping amount of lithium was 2%. The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope.

Moreover, it was confirmed that the peaks attributable to silicon, lithium silicate, and lithium aluminate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 10 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0, and thus the generation of SiC was suppressed. The x-ray diffraction chart thereof is shown in FIG. 2.

Example 3

Metallic silicon and silicon dioxide were blended at a molar ratio of 1:1, and reacted at 1400° C. under a reduced pressure of 100 Pa to generate a silicon oxide gas. The gas was blended with a silicon gas that was generated by heating metallic silicon to 2000° C. The blended gas was cooled to 900° C. under a reduced pressure of 50 Pa to precipitate, and a product in mass form was consequently obtained. The product was pulverized with a dry-type ball mill to obtain silicon-silicon oxide composite powder having an average particle size of 5 μm.

Chemical analysis revealed that the composition of this silicon-silicon oxide composite powder was SiO_(0.5), the structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, and the powder was thus silicon-silicon oxide composite. The size of silicon crystal of this silicon-silicon oxide composite was 5 nm.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same conditions as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1 except for a condition of lithium hydride:silicon-silicon oxide composite (except carbon)=1:20 (a mass ratio).

The doping amount of lithium of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 5%. The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the powder.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 14 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0, and thus the generation of SiC was suppressed.

Example 4

Metallic silicon and silicon dioxide were blended at a molar ratio of 1:1, and reacted at 1400° C. under a reduced pressure of 100 Pa to generate a silicon oxide gas. The gas was blended with an oxygen gas at a molar ratio of 10:1. The blended gas was cooled to 900° C. under a reduced pressure of 50 Pa to precipitate, and a product in mass form was consequently obtained. The product was pulverized with a dry-type ball mill to obtain silicon-silicon oxide composite powder having an average particle size of 5 μm.

Chemical analysis revealed that the composition of this silicon-silicon oxide composite powder was SiO_(1.5), the structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, and the powder was thus silicon-silicon oxide composite. The size of silicon crystal of this silicon-silicon oxide composite was 3 nm.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same conditions as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1.

The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 10 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0, and thus the generation of SiC was suppressed.

Example 5

Metallic silicon and silicon dioxide were blended at a molar ratio of 1:1, and reacted at 1400° C. under a reduced pressure of 100 Pa to generate a silicon oxide gas. The gas was cooled to 600° C. under a reduced pressure of 50 Pa to precipitate, and a product in mass form was consequently obtained. The product was pulverized with a dry-type ball mill to obtain powder having an average particle size of 5 μm.

Chemical analysis revealed that the composition of this powder was SiO_(0.95), the structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was not observed with a transmission electron microscope, and the powder was thus silicon oxide (there is no disproportionation to silicon-silicon oxide). The diffraction peak of Si (111) face was not observed in the silicon oxide, when the x-ray diffraction using Cu—Kα ray.

The silicon oxide powder was subjected to the heat CVD treatment in the same conditions as Example 1 except for a treatment temperature of 800° C. and a treatment time of 120 hours, and the powder having the carbon coating formed thereon at a carbon coating amount of 5% was obtained.

Next, the powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1.

The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 1 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0, and thus the generation of SiC was suppressed.

Example 6

Powder of the silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1 except for a treatment temperature of 1200° C. and a treatment time of 2 hours, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same condition as Example 1.

The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 23 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0.019, and thus the generation of SiC was suppressed.

Example 7

Powder of the silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same condition as Example 1 except for a reaction temperature of 300° C. and a reaction time of 20 hours.

The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 9 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0, and thus the generation of SiC was suppressed.

Example 8

Powder of the silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same condition as Example 1 except for a reaction temperature of 800° C. and a reaction time of 10 minutes.

The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 25 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0, and thus the generation of SiC was suppressed.

Example 9

Powder of the silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same condition as Example 1 except for a condition of lithium hydride:silicon-silicon oxide composite (except carbon)=1:100 (a mass ratio).

The doping amount of lithium of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 1%. The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the negative electrode material.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 8 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0, and thus the generation of SiC was suppressed.

Example 10

Powder of the silicon-silicon oxide composite having a composition of SiO_(1.5) and a silicon crystal size of 3 nm was obtained by the same method as Example 4.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same condition as Example 1 except for a condition of lithium hydride:silicon-silicon oxide composite (except carbon)=1:4 (a mass ratio).

The doping amount of lithium of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 16%. The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the powder.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 30 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0.008, and thus the generation of SiC was suppressed.

Example 11

Powder of the silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1 except for a treatment time of 1 hour, and the silicon-silicon oxide composite powder having the carbon coating formed thereon with a carbon coating amount of 1% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same condition as Example 1.

The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 10 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0, and thus the generation of SiC was suppressed.

Example 12

Powder of the silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1 except for a treatment time of 63 hours, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 40% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same condition as Example 1.

The structure that silicon particles were dispersed to silicon oxide in an atomic order and/or a crystallite state was observed with a transmission electron microscope, in the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above.

Moreover, it was confirmed that the peaks attributable to silicon and lithium silicate were observed when the x-ray diffraction using Cu—Kα ray, the size of silicon crystal was 13 nm, and thus the growth of the silicon crystal was suppressed. It was further confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0.011, and thus the generation of SiC was suppressed.

Comparative Example 1

Powder of a silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was consequently obtained. The size of silicon crystal of the silicon-silicon oxide composite was 7 nm.

The powder was used for a negative electrode material for a secondary battery with a non-aqueous electrolyte without doping with lithium.

Comparative Example 2

Except that, in Example 1, the order of a heat CVD process (at a temperature of 1100° C., for 5 hours) and a process of doping with lithium (use of lithium hydride, lithium hydride:silicon-silicon oxide composite=1:10, a holing time of 1 hour at a temperature of 600° C.) was reversed, a negative electrode material for a secondary battery with a non-aqueous electrolyte was manufactured in the same condition as Example 1, and the same evaluation was carried out.

It was revealed that the size of silicon crystal was 37 nm from the result of the x-ray diffraction using Cu—Kα ray of the obtained negative electrode material for a secondary battery with a non-aqueous electrolyte, and thus the growth of silicon crystal was considerably accelerated due to lithium.

It was confirmed that the ratio satisfied a relation of I(SiC)/I(Si)=0.034, and thus SiC was largely generated. The x-ray diffraction chart thereof is shown in FIG. 3. In FIG. 3, a peak attributable to SiC is observed.

Comparative Example 3

Powder of a silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon with a carbon coating amount of 5% was consequently obtained.

Next, 28.4 g of the silicon-silicon oxide composite powder having the carbon coating formed thereon was put into a 200 g glass jar and 2.7 g stabilized lithium powder SLMP made by FMC Corp. was further added thereto, in a glove box under an argon atmosphere. It was blended by manually shaking after putting the lid so as to be uniform.

The blend was put into an iron mortar having an internal volume of 1000 ml, and was stirred with a pestle. At this point, ignition reaction with light emission happened at the vicinity of a contact portion of a surface of the mortar with the pestle. Unreacted portions at the periphery is thereupon moved thereon with a spatula so that this reaction eventually prevailed uniformly throughout the mortar. After it was sufficiently cooled, the product was fully disintegrate and taken out of the glove box.

It was revealed that the size of silicon crystal of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 81 nm, and the silicon crystal was largely grown.

Comparative Example 4

Powder of a silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was consequently obtained.

Next, 2.7 g powder of lithium hydroxide (reagent made by Wako Pure Chemical Industries, Ltd.) was put into a porcelain mortar having an internal volume of 500 ml and pulverized in a glove box under a dry air atmosphere. Thereafter, 28.4 g of the silicon-silicon oxide composite powder having the carbon coating formed thereon was added thereto, and they were stirred and blended so as to be sufficiently uniform.

The blend of 29 g was transferred to a 70 ml alumina boat and the boat was carefully placed at the center of a furnace tube of an electric tube furnace provided with an alumina furnace tube having an inner diameter of 50 mm. It was heated up to 900° C. at 5° C. every minute while passing an argon gas at 2 liters every minute, and was cooled after holding of 1 hour.

It was revealed that the size of silicon crystal of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 68 nm, and the silicon crystal was largely grown.

Comparative Example 5

Powder of a silicon-silicon oxide composite having a composition of SiO_(0.3) was obtained by the same method as Example 3 except that the temperature of heating metallic silicon was 2100° C.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same conditions as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1 except for a condition of lithium hydride:silicon-silicon oxide composite (except carbon)=1:20 (a mass ratio) to obtain a negative electrode material for a secondary battery with a non-aqueous electrolyte.

Comparative Example 6

Powder of a silicon-silicon oxide composite having a composition of SiO_(1.7) was obtained by the same method as Example 4 except that the molar ratio of a silicon oxide gas to an oxygen gas was 10:2.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same conditions as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1 to obtain a negative electrode material for a secondary battery with a non-aqueous electrolyte.

Comparative Example 7

Silicon oxide powder (there is no disproportionation to silicon-silicon oxide) was obtained by the same method as Example 5.

The silicon oxide powder was subjected to the heat CVD treatment in the same conditions as Example 1 except for a treatment temperature of 750° C. and a treatment time of 200 hours, and the powder having the carbon coating formed thereon at a carbon coating amount of 5% was obtained.

Next, the powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1 except for a reaction temperature of 300° C. and a reaction time of 20 hours.

The doping amount of lithium of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 8%. It was revealed that the size of silicon crystal of the powder was 0.4 nm, and the silicon crystal was not sufficiently grown.

Comparative Example 8

Powder of a silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1 except for a treatment temperature of 1350° C. and a treatment time of 40 minutes, and the silicon-silicon oxide composite powder having the carbon coating formed thereon with a carbon coating amount of 5% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same condition as Example 1.

It was revealed that the size of silicon crystal of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 52 nm, and the silicon crystal was largely grown.

Comparative Example 9

Powder of a silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same conditions as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 5% was obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was heated together with lithium hydride in the same conditions as Example 1 except for a heating temperature of 100° C. and a heating time of 40 hours.

It was revealed that the doping amount of lithium of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 0%, and thus the lithiation reaction did not happen.

Comparative Example 10

Powder of a silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same conditions as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon with a carbon coating amount of 5% was obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1 except for a reaction temperature of 900° C. and a reaction time of 10 minutes.

It was revealed that the size of silicon crystal of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 85 nm, and the silicon crystal was largely grown.

Comparative Example 11

Powder of a silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same conditions as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon with a carbon coating amount of 5% was obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1 except for a condition of lithium hydride:silicon-silicon oxide composite (except carbon)=1:2000 (a mass ratio).

The doping amount of lithium of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 0.05%

Comparative Example 12

Powder of a silicon-silicon oxide composite having a composition of SiO_(1.5) and having a size of 3 nm was obtained by the same method as Example 4.

The silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same conditions as Example 1, and the silicon-silicon oxide composite powder having the carbon coating formed thereon with a carbon coating amount of 5% was obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1 except for a condition of lithium hydride:silicon-silicon oxide composite (except carbon)=2:5 (a mass ratio).

The doping amount of lithium of the negative electrode material for a secondary battery with a non-aqueous electrolyte obtained as above was 23%

Comparative Example 13

Powder of a silicon-silicon oxide composite having a silicon crystal size of 4 nm was obtained by the same method as Example 1.

This silicon-silicon oxide composite powder was subjected to the heat CVD treatment in the same condition as Example 1 except for a treatment time of 96 hours, and the silicon-silicon oxide composite powder having the carbon coating formed thereon at a carbon coating amount of 50% was consequently obtained.

Next, the silicon-silicon oxide composite powder having the carbon coating formed thereon was reacted with lithium hydride in the same conditions as Example 1 to obtain a negative electrode material for a secondary battery with a non-aqueous electrolyte.

(Battery Evaluation)

The evaluation as the negative electrode active material for a lithium ion secondary battery was carried out by the following method/procedure which was common to all Examples and Comparative Examples.

A blend was first produced by adding flake synthetic graphite powder (average particle diameter D₅₀=5 μm) to 20 g of the obtained negative electrode material for a secondary battery with a non-aqueous electrolyte in such amounts that the total of carbon in flake synthetic graphite and the carbon coating formed on the negative electrode material for a secondary battery with a non-aqueous electrolyte was 42%.

Binder KSC-4011 made by Shin-Etsu Chemical Co., Ltd. was added in an amount of 10% as solids to the blend to form a slurry below 20° C. N-methylpyrrolidone was further added for viscosity adjustment. This slurry was speedily coated onto a copper foil having a thickness of 20 μm and dried at 120° C. for 1 hour. An electrode was thereafter formed by pressing with a roller press and finally punched out so as to have a size of 2 cm² as the negative electrode. At this point in time, the mass of the negative electrode was measured to calculate the mass of the negative electrode material by subtracting the mass of the copper foil, flake synthetic graphite powder, and the binder therefrom.

To evaluate the charge/discharge characteristics of the obtained negative electrode, a lithium-ion secondary battery for evaluation was fabricated using a lithium foil as a counter electrode; using, as a non-aqueous electrolyte, a non-aqueous electrolyte solution obtained by dissolving lithium hexafluorophosphate in a 1/1 (a volume ratio) mixture of ethylene carbonate and 1,2-dimethoxyethane at a concentration of 1 mol/L; and using a polyethylene microporous film having a thickness of 30 μm as a separator.

The fabricated lithium-ion secondary battery was allowed to stand overnight at room temperature. Thereafter, with a secondary battery charge/discharge test apparatus (made by Nagano, Co., Ltd.), the battery for evaluation was charged at a constant current of 1.5 mA until the test cell voltage reached 5 mV at room temperature. After the voltage reached 5 mV, the battery was charged at a reduced current so that the cell voltage was maintained at 5 mV. When the current value had decreased below 200 μA, the charging was terminated. The battery was discharged at a constant current of 0.6 mA, and the discharging was terminated when the cell voltage reached 2.0 V.

The charge/discharge capacity per unit mass of the negative electrode material were calculated by subtracting the charge/discharge capacity of the flake synthetic graphite powder from the above-obtained charge/discharge capacity.

capacity per mass(mAh/g)=discharge capacity of negative electrode material(mAh)/mass of negative electrode material(g)

first efficiency(%)=discharge capacity of negative electrode material mAh)/charge capacity of negative electrode material(mAh)×100

The charge/discharge test of the lithium-ion secondary battery for evaluation was carried out 50 times by repeating the charge/discharge test as above, to evaluate the cycle durability.

capacity retention ratio (%)=discharge capacity of negative electrode material after 50 cycles (mAh)/first discharge capacity of negative electrode material (mAh)×100

Table 1 shows the result of evaluating the negative electrode material for a secondary battery with a non-aqueous electrolyte in Examples 1 to 12 and Comparative Examples 1 to 13 by the above-described method.

TABLE 1 CAPACITY CAPACITY FIRST RETENTION PER MASS EFFICIENCY RATE (mAh/g) (%) (%) RESULT EXAMPLE 1 1370 85 89 GOOD EXAMPLE 2 1430 76 89 GOOD EXAMPLE 3 1990 91 81 GOOD EXAMPLE 4 950 72 93 GOOD EXAMPLE 5 1320 83 90 GOOD EXAMPLE 6 1400 85 82 GOOD EXAMPLE 7 1360 85 89 GOOD EXAMPLE 8 1380 84 83 GOOD EXAMPLE 9 1480 73 89 GOOD EXAMPLE 10 850 95 90 GOOD EXAMPLE 11 1420 85 85 GOOD EXAMPLE 12 870 85 93 GOOD COMPARATIVE 1500 66 90 PARTICULARLY LOW EXAMPLE 1 FIRST EFFICIENCY COMPARATIVE 1320 84 35 PARTICULARLY EXAMPLE 2 INFERIOR CYCLE DURABILITY COMPARATIVE 1380 87 58 INFERIOR CYCLE EXAMPLE 3 DURABILITY COMPARATIVE 1170 74 63 INFERIOR CYCLE EXAMPLE 4 DURABILITY COMPARATIVE 2310 97 54 INFERIOR CYCLE EXAMPLE 5 DURABILITY COMPARATIVE 780 68 93 LOW CAPACITY EXAMPLE 6 COMPARATIVE 1260 69 91 LOW FIRST EXAMPLE 7 EFFICIENCY COMPARATIVE 1390 86 66 INFERIOR CYCLE EXAMPLE 8 DURABILITY COMPARATIVE 1500 66 89 PARTICULARLY LOW EXAMPLE 9 FIRST EFFICIENCY COMPARATIVE 1250 84 54 INFERIOR CYCLE EXAMPLE 10 DURABILITY COMPARATIVE 1490 69 90 LOW FIRST EXAMPLE 11 EFFICIENCY COMPARATIVE 730 65 53 INFERIOR CYCLE EXAMPLE 12 DURABILITY COMPARATIVE 690 85 93 LOW CAPACITY EXAMPLE 13

As shown in Table 1, it was revealed that the cases of the negative electrode materials in Examples 1 to 13 showed a good value of each of the capacity per mass, the first efficiency, the capacity retention ratio after 50 cycles (cycle durability), the cases where every one of the size of the silicon particles dispersed to silicon oxide in an atomic order and/or a crystallite state, the Si/O molar ratio, the coating amount of the carbon coating with respect to the amount of the silicon-silicon oxide composite, the doping amount of lithium with respect to the amount of the silicon-silicon oxide composite, I(SiC)/I(Si) satisfied values of the present invention.

On the other hand, it was revealed that the case of Comparative Example 1, where the doping with lithium was not performed, showed inferior first efficiency, and that the case of Comparative Example 2, where the carbon coating was formed after doping with lithium and the value of I(SiC)/I(Si) exceeded 0.03, showed the cycle durability inferior to the other negative electrode materials and a large amount of SiC generation, whereas the capacity per mass and the first efficiency had no problem, and thus had characteristic problems for the negative electrode material.

Moreover, the cases of Comparative Examples 3 to 13 showed the following result. Since the doping with lithium was performed after coating with carbon except for Comparative Example 9, where the lithiation reaction did not happen, the generation of SiC was suppressed, and the cycle durability was superior to the case of Comparative Example 2 that is a conventional method. Since terms and conditions defined in the present invention were not satisfied, the cycle durability was inferior to Examples. Hereinafter, the cases will be individually explained.

In Comparative Example 3, where the lithium powder was used as the lithium dopant, silicon crystal particles were excessively grown due to the ignition reaction in the process of doping with lithium, and the cycle durability thereby became inferior. The case of Comparative Example 4, where lithium hydroxide was used as the lithium dopant, needed a high temperature for the doping treatment with lithium, thereby the size of silicon crystal contained in the negative electrode material became too large, and the cycle durability consequently became inferior.

In Comparative Example 5, there was a shortage of oxygen (less than 0.5) in the silicon-silicon oxide composite, and thereby the cycle durability was inferior. In Comparative Example 6, there was an excessive oxygen (more than 1.6), and thereby the capacity became low, whereas the cycle durability was good.

In Comparative Example 7, the growth of silicon crystal was insufficient (the size of the silicon particles was less than 0.5 nm), and thereby the first efficiency was low. In Comparative Example 8, the size of the crystal was too large (the size of the silicon particles was more than 50 nm), and thereby the cycle durability was inferior.

In Comparative Example 9, the heating temperature of the doping treatment with lithium was less than 200° C., thereby the lithiation reaction did not happen, and the first efficiency was low. In Comparative Example 10, the heating temperature was more than 800° C., thereby silicon crystal was largely grown, and the cycle durability became inferior.

In Comparative Example 11, the doping amount of lithium was low (less than 0.1 mass %) and thereby the first efficiency was low. In Comparative Example 12, the doping amount of lithium was high (more than 20 mass %), thereby the reactivity was high, there happened a trouble with adhesion to the binder when a battery was fabricated, and the cycle durability consequently became inferior.

In Comparative Example 13, the carbon coating amount was high (40 mass % or more), thereby the amount ratio of the silicon-silicon oxide composite doped with lithium was low, and thereby the capacity was low, whereas the cycle durability was good.

It is to be noted that the present invention is not restricted to the foregoing embodiment. The embodiment is just an exemplification, and any examples that have substantially the same feature and demonstrate the same functions and effects as those in the technical concept described in claims of the present invention are included in the technical scope of the present invention. 

What is claimed is:
 1. A negative electrode material for a secondary battery with a non-aqueous electrolyte comprising at least: a silicon-silicon oxide composite having a structure that silicon particles having a size of 0.5 to 50 nm are dispersed to silicon oxide in an atomic order and/or a crystallite state, the silicon-silicon oxide composite having a Si/O molar ratio of 1/0.5 to 1/1.6; and a carbon coating formed on a surface of the silicon-silicon oxide composite at a coating amount of 1 to 40 mass % with respect to an amount of the silicon-silicon oxide composite, wherein at least the silicon-silicon oxide composite is doped with lithium at a doping amount of 0.1 to 20 mass % with respect to an amount of the silicon-silicon oxide composite, and a ratio I(SiC)/I(Si) of a peak intensity I(SiC) attributable to SiC of 2θ=35.8±0.2° to a peak intensity I(Si) attributable to Si of 2θ=28.4±0.2° satisfies a relation of I(SiC)/I(Si)≦0.03, when x-ray diffraction using Cu—Kα ray.
 2. The negative electrode material for a secondary battery with a non-aqueous electrolyte according to claim 1, wherein a peak attributable to lithium aluminate is further observed in the negative electrode material for a secondary battery with a non-aqueous electrolyte, when the x-ray diffraction using Cu—Kα ray.
 3. A lithium ion secondary battery having at least a positive electrode, a negative electrode, and a non-aqueous electrolyte having lithium ion conductivity, wherein the negative electrode material for a secondary battery with a non-aqueous electrolyte according to claim 1 is used for the negative electrode.
 4. A lithium ion secondary battery having at least a positive electrode, a negative electrode, and a non-aqueous electrolyte having lithium ion conductivity, wherein the negative electrode material for a secondary battery with a non-aqueous electrolyte according to claim 2 is used for the negative electrode.
 5. A method for manufacturing a negative electrode material for a secondary battery with a non-aqueous electrolyte comprising at least: coating a surface of powder with carbon at a coating amount of 1 to 40 mass % with respect to an amount of the powder by heat CVD treatment under an organic gas and/or vapor atmosphere at a temperature between 800° C. and 1300° C., the powder being composed of at least one of silicon oxide represented by a general formula of SiO_(x) (x=0.5 to 1.6) and a silicon-silicon oxide composite having a structure that silicon particles having a size of 50 nm or less are dispersed to silicon oxide in an atomic order and/or a crystallite state, the silicon-silicon oxide composite having a Si/O molar ratio of 1/0.5 to 1/1.6; blending lithium hydride and/or lithium aluminum hydride with the powder coated with carbon; and thereafter heating the powder coated with carbon at a temperature between 200° C. and 800° C. to be doped with lithium at a doping amount of 0.1 to 20 mass % with respect to an amount of the powder. 